I'm not sure if the first picture is Tourmaline, corundum or something different. They have a lot of flaws and inclusions.
The second picture is listed as Ruby Corundum in Chrome Diopside Matrix. It looks correct and could fetch a decent amount of money to the right person. Where did you get them?
Well, that's good for you. I would take that corundum and any other good looking specimens to a registered gemologist and get a positive identification!
The upper pictures are watermelon tourmaline and might fetch a good deal with a gem cutter. The ruby specimens will be worth something to a collector and its good you have a tag for them. Nice finds from a garage sale.