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Depends on the ore as to which is best used ratled. I don't know of any effective direct stamp mill cyanide treatments ever being used commercially. Mercury amalgamation is commonly used just past the stamp mill in the grind amalgamation cup or on slick plates
Free milling ore with mercury amalgamation is cheaper and easier than cyanide. If the ore has sulfides mercury won't work. If the ores have silver or several other minerals cyanide won't be effective.
For processing those deposits with sulfides the cyanidation process was discovered around 1887. It didn't take long for mines with ores that needed cyanide treatment to begin using it. The Forrest Process was in popular use by 1890.
Cyanidation became the dominant process because all those worked out free milling orogenic deposits could be worked again in their sulfide ores at depth. Not because it was any more effective at treating free milling gold ores but because the deeper sulfide bound gold ores couldn't be processed effectively with mercury. Some old tailings became valuable too.
Free milling gold ores as well as silver and copper tend to slow the cyanide process down to where it's not very effective. Often the situation is much more complex than a simple cyanide treatment. Pretreatments are often necessary to prepare the milled ore for the cyanide beds.
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