I will give it a shot. I'm guessing #1 is a 45-70 405gr. #2 # 3 9mm pistol slugs. #4 9mm or 38 pistol. #5 & 6 44 cal. round balls for pistol.
The 45-70 first appeared in 1873, still loaded today. 9mm the late 1890's to present. .38 1880 to present. The round balls could date 1840-1920 period. Nice finds