Hey epidote:
Some very interesting mineral photos and they diffidently warrant a closer "look-see". But, unless I completely misunderstood your intentions, if you are thinking about going to a direct melt/smelt to extract the precious metals from these minerals, it isn't going to happen.
The main purpose of a flux is to improve the flow of the melt and in some cases, to slag off small amounts of impurities. If the bulk of your melt is precious metals, there is a "verifiable" flux used by the U.S. Mint to oxidies off the contaminates. But, if the bulk of your melt is a base metal, there is no flux to slag off the precious metals.
At high temperatures, all the metals will mix or alloy together, inhibiting any form of seperation. You might be able to use a collector like lead (Pb) or bismuth (Bi), as done in a fire assay, but with bulk iron melts that is seldom economically fesible. And then, there's the sulfur problem.
Speaking of bulk melts, how much of this material do you have? There's always a way to extract precious metals from an ore, but I don't think direct pyrometallurgy is the answer in this case. Give us some more info on your ore and we should be able to come up with a better answer.
Good luck,
John