Electrolysis 101

greydigger

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Mar 28, 2008
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Hello folks,
Beem wading through the threads here and this is what I have gleaned.
Someone else I am sure said it better and I maybe wrong on somethings.
Please let me know.

The use of electricity to clean metals (sometimes found in the ground) is based on the action of (atoms/molecules?)
to travel from negative to positive using D.C. current. The + thing is called a cathode and the - thing is called an anode.
( 50/50 chance I am right eh?) Someone please let me know.
This action takes the outside stuff from the object needing cleaning to another object that we don't care about.
Now both of these objects need to be able to conduct electricity.

Someone said that more noble metals do better at something than lesser noble metals but I forget what that means,
maybe where there is no induced electricity in the bath.
I do know that "sacrificial zincs" are attached to boats to keep the steel propellers from "rotting" away.

So as I understand, the + can be anything and the - can be anything.
The + has been suggested to be conductive graphite for a reason I don't know.
Perhaps it is easier to clean. Some have used old saw blades, some stainless steel.
Does this have to do to the noble/ignoble thing?

Another post suggested you could "plate" a + item with a - item.
I.E. use a silver spoon as a - and a copper penny as a + and you have a silver plated penny.
That's neat.
From that I can infer that anything conducting electricity will go that way.
Except for the noble/ignoble metals. How does that work out?

I have sent many aluminum items to an anodiser to put a hard coating on them and could specify how thick the coating was.
Colors optional and made some pretty tooling.
.0005 inches thick of plating was a lot. Usually less.
I am thinking they used electrolysis for this.

Any thoughts?

Grey
 

Cathode and anode can either be positive or negative depending on what your doing.. But I believe your correct in this application..
This is the misconception of electrolysis process, the surface of the metal being cleaned (-) is moved into solution and travels to the + post.. Most of the crud actually falls off because the surface layer of metal it is adhered to is removed..
They all need to conduct..object to be cleaned(anode), the solution(why we add chemicals to the water) and sacrificial cathode..
Noble metals don't oxidize so the don't give up parts of itself as easily..
The graphite works better because its easier to clean as the stainless gets coated with crud that doesn't come off as its bonded together...
As far as plating goes it is more of a chemical process that helps holds the metal in solution(more so noble metals) the electricity just more of a transportation device.. The silver collected on the cathode would be black instead of silver looking by trying to plate with the solutions what we use here.. The silver oxide would need to be refined..
Anodizing is using electrolysis to form a oxide coating made of the metal itself.. Kind of creating space (between molecules) on the surface.. The dyes can be added to color..Sometimes the color is not a dye but a altered surface by chemical means to refract light differently..
Ray
 

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