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Cool find! Any recorded history to the property? I found a couple early printing plates last year with portraits on them. They don't come around very often.
I believe you have an early pre-CW era Ambrotype. The film was actually the glass! The emulsions were applied to the glass and the picture exposed directly to it.
Unfortunately War images that used those types of processes and later those that used glass as negatives were lost, because after the Civil War, many Americans didn't want to see the war pictures anymore, so the glass was sold to homeowners and esp. those with greenhouses and the sun on the glass eventually bleached out years of American history. There were thousands more pictures of that period, than are left today, because of this sad act. That is a very neat find!
A Civil War soldier suffering cold, hunger, fatigue, sickness, thirst, and a host of other discomforts and ailments, only had to reach into his pack, pull out the picture of his loved one at home, glance at her stern unsmiling features and say to himself - Yeah, I did the right thing joining the Army...